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金泽祥, 汤志勇. 萃取富集—ICP—AES测定地质样品中痕量镓铟铊[J]. 岩矿测试, 1991, (2): 100-102.
引用本文: 金泽祥, 汤志勇. 萃取富集—ICP—AES测定地质样品中痕量镓铟铊[J]. 岩矿测试, 1991, (2): 100-102.
Determination of Trace Ga,In and Tl in Geological Samples by Stepwise Extraction-ICP-AES[J]. Rock and Mineral Analysis, 1991, (2): 100-102.
Citation: Determination of Trace Ga,In and Tl in Geological Samples by Stepwise Extraction-ICP-AES[J]. Rock and Mineral Analysis, 1991, (2): 100-102.

萃取富集—ICP—AES测定地质样品中痕量镓铟铊

Determination of Trace Ga,In and Tl in Geological Samples by Stepwise Extraction-ICP-AES

  • 摘要: 本文研究了分步萃取-ICP-AES法测定地质试样中痕量Ga、In和Tl的最佳条件。首先在pH9左右,用吡咯烷二硫代氨基甲酸铵(APLC)-甲基异丁酮(MIBK)萃取In和Tl,然后在6mol/LHCl介质中用MIBK萃取Ga,再将有机相分别直接引入ICP-AES进行测定。方法较简便实用,经地质标样验证,结果满意。

     

    Abstract: Optimal conditions were investigated for the determination of gallium, indium and thallium by stepwise extraction-ICP-AES. Indium and thallium were first extracted with APDG-MIBK from pH 9 solution, then gallium was extracted into MIBK from 6mol/L HC1 med

     

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