【引用本文】 张健, 陈华, 陆太进, 等. 山东金刚石碳同位素组成的二次离子质谱显微分析[J]. 岩矿测试, 2012, 31(4): 591-596.
 ,  ,  , et al. Microanalysis of the Carbon Isotopic Composition in Diamonds from Shangdong of China by Secondary Ion Mass Spectrometry[J]. Rock and Mineral Analysis, 2012, 31(4): 591-596.

山东金刚石碳同位素组成的二次离子质谱显微分析

1. 

国土资源部珠宝玉石首饰管理中心, 北京 100013

2. 

国土资源部珠宝玉石首饰管理中心, 北京 100013

3. 

国土资源部珠宝玉石首饰管理中心, 北京 100013

4. 

中山大学地球科学系, 广东 广州 510275

5. 

国土资源部珠宝玉石首饰管理中心, 北京 100013

6. 

国土资源部珠宝玉石首饰管理中心, 北京 100013

收稿日期: 2011-11-29 

基金项目: 国土资源部公益性行业科研专项(200811012)

Microanalysis of the Carbon Isotopic Composition in Diamonds from Shangdong of China by Secondary Ion Mass Spectrometry

1. 

National Gems & Jewelry Technology Administrative Center, Beijing 100013, China

2. 

National Gems & Jewelry Technology Administrative Center, Beijing 100013, China

3. 

National Gems & Jewelry Technology Administrative Center, Beijing 100013, China

4. 

Department of Earth Science, Sun Yat-sen University, Guangzhou 510275, China

5. 

National Gems & Jewelry Technology Administrative Center, Beijing 100013, China

6. 

National Gems & Jewelry Technology Administrative Center, Beijing 100013, China

Received Date: 2011-11-29

摘要:华北克拉通山东金刚石晶体生长的多阶段性及碳同位素组成已被人们关注,但很少有人对不同阶段金刚石及其内部的碳同位素组成变化进行分析。本文利用二次离子质谱(SIMS)微区分析技术对山东金刚石晶体内部不同阶段生长的δ13C进行了原位测试分析,得出山东金刚石δ13C的变化范围在-5.6‰~-2.01‰,平均值为-3.63‰,与前人对华北克拉通金刚石碳同位素组成测试值(δ13C在-14.71‰~-0.46‰,主要集中在-9‰~-4‰之间)大致相同,位于全球橄榄岩型金刚石及幔源碳同位素组成主要范围(-8‰~-2‰)内。结合金刚石生长环带阴极发光图像,认为金刚石自核心部位至边缘,在同一期生长环带内,其δ13C值呈变重趋势;在多期复杂生长环带之间,δ13C值因结晶时的地质环境不同而存在差异。δ13C值的这种变化揭示了该地区金刚石复杂的生长环境,为解析华北克拉通地幔碳循环提供了定量数据。

关键词: 金刚石, 碳同位素, 地球化学, 二次离子质谱

Microanalysis of the Carbon Isotopic Composition in Diamonds from Shangdong of China by Secondary Ion Mass Spectrometry

KEY WORDS: diamond, carbon, isotope, geochemistry

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山东金刚石碳同位素组成的二次离子质谱显微分析

张健, 陈华, 陆太进, 丘志力, 魏然, 柯捷