【引用本文】 吉昂, . X射线荧光光谱三十年[J]. 岩矿测试, 2012, 31(3): 383-398.
 . Development of X-ray Fluorescence Spectrometry in the 30 Years[J]. Rock and Mineral Analysis, 2012, 31(3): 383-398.

X射线荧光光谱三十年

中国科学院上海硅酸盐研究所, 上海 200050

收稿日期: 2012-02-29 

Development of X-ray Fluorescence Spectrometry in the 30 Years

Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai 200050, China

Received Date: 2012-02-29

摘要:X射线荧光光谱分析在20世纪80年代初已是一种成熟的分析方法,是实验室、现场分析主、次量和痕量元素的首选方法之一,在无损分析和原位分析中具有不可替代的地位。文章评述了三十年来X射线荧光光谱分析的进展历程、波长色散X射线荧光光谱仪(WDXRF)、能量色散X射线荧光光谱仪(EDXRF)和现场与原位分析用X射线荧光光谱仪发展过程及显示的特色。介绍了在X射线的全反射和偏振性质基础上相继推出的偏振、微束、全反射等全新的X射线荧光光谱仪及其在众多领域的应用。回顾了基体校正发展历程和以Sherman方程为基础的基本参数法和理论影系数法在定量分析中的应用,并对学术界有关基体校正的物理意义的争论、Sherman方程的局限性以及如何提高基本参数法在常规定量分析和半定量分析结果的准确度的途径进行了探讨。总结了化学计量学与数据处理方法在XRF中的应用研究及进展,指出人工神经网络方法与基本参数法相结合的算法,对于改善基体校正的准确度和稳定性开创了一条新的途径。

关键词: X射线荧光光谱分析, 三十年, 基体校正, 化学计量学

Development of X-ray Fluorescence Spectrometry in the 30 Years

KEY WORDS: X-ray, fluorescence, spectrometry, analysis

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便携式X荧光仪在铅锌矿评价野外工作中的应用[J]. 夏天,牛辉,刘毅业.  西部探矿工程. 2016(07)

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提高熔片X射线荧光法测定钼精矿中Mo等多种元素准确度[J]. 高会艳,刘丙森,李志明,杨凤云.  化工管理. 2016(03)

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基于小波变换的X荧光能谱的解析[D]. 杨中建.成都理工大学 2014

[32]

现代分析技术在稀土元素原位分析中的应用[J]. 段益琴,桑世华,李崇瑛,李诚,王伟.  中国锰业. 2016(05)

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基于激光诱导等离子体光谱的真空环境熔融金属成分在线检测技术研究[D]. 潘从元.中国科学技术大学 2015

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牛津仪器公司XRF光谱仪营销策略研究[D]. 谢灿华.广西大学 2015

[35]

火山泥金属元素种类、含量和菌落分析[J]. 姜莹芳,尹兆明,张亚刚,王彩云,曹嘉洌.  日用化学工业. 2016(12)

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白云鄂博矿有价元素的X荧光快速测量[D]. 赵德胜.内蒙古科技大学 2015

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X射线荧光光谱三十年

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