【引用本文】 路国慧, 沈亚婷, 何俊, 等. 高效液相色谱-串联质谱法测定黄河河口段水中全氟化合物的初步研究[J]. 岩矿测试, 2012, 31(1): 147-153.
 ,  ,  , et al. Preliminary Study on Perfluorinated Compounds in Waters from the Yellow River Estuary Area by Utilizing Liquid Chromatography-Mass Spectrometry/Mass Spectrometry[J]. Rock and Mineral Analysis, 2012, 31(1): 147-153.

高效液相色谱-串联质谱法测定黄河河口段水中全氟化合物的初步研究

1. 

国家地质实验测试中心, 北京 100037

2. 

国家地质实验测试中心, 北京 100037

3. 

中国环境科学研究院, 北京 100012

4. 

青岛大学化学化工与环境学院, 山东 青岛 266071

5. 

国家地质实验测试中心, 北京 100037

6. 

国家地质实验测试中心, 北京 100037

收稿日期: 2011-12-06 

基金项目: 国家地质实验测试中心基本科研业务费项目(201012CSJ05)

Preliminary Study on Perfluorinated Compounds in Waters from the Yellow River Estuary Area by Utilizing Liquid Chromatography-Mass Spectrometry/Mass Spectrometry

1. 

National Research Center for Geoanalysis, Beijing 100037, China

2. 

National Research Center for Geoanalysis, Beijing 100037, China

3. 

Chinese Research Academy of Environmental Sciences, Beijing 100012, China

4. 

College of Chemical and Environmental Engineering, Qingdao University, Qingdao 266071, China

5. 

National Research Center for Geoanalysis, Beijing 100037, China

6. 

National Research Center for Geoanalysis, Beijing 100037, China

Received Date: 2011-12-06

摘要:以近年来备受关注的持久性有机污染物——全氟化合物为研究目标物,黄河河口段为目标研究区域,应用高效液相色谱-串联质谱法测定黄河河口段河水、自来水和浅层地下水中的19种全氟化合物含量,描述研究该区域水体中全氟化合物的污染水平和分布规律,并探讨水体中全氟化合物的来源。结果表明,全氟丁酸和全氟辛酸是黄河河口段水体中最主要的全氟化合物,黄河水中的全氟丁酸和全氟辛酸浓度分别为1.61~4.20 ng/L和 2.04~3.36 ng/L。浅层地下水中各待测物检出率都很低;自来水中全氟丁酸和全氟辛酸的浓度分别为1.62~3.24 ng/L和 4.66~9.34 ng/L;自来水与黄河水中全氟化合物的组成特征明显不同。东营地区黄河水中全氟辛烷磺酸的浓度与国内其他北方城市相比浓度相当,明显低于长江水和珠三角地表水;全氟辛酸的浓度与呼和浩特市周边河水以及北京官厅水库中浓度相当,相比国内其他地区处于较低水平。

关键词: 高效液相色谱-串联质谱法, 全氟化合物, 黄河河口区, 河水, 自来水, 浅层地下水

Preliminary Study on Perfluorinated Compounds in Waters from the Yellow River Estuary Area by Utilizing Liquid Chromatography-Mass Spectrometry/Mass Spectrometry

KEY WORDS: liquid, chromatography-mass, spectrometry/mass, spectrometry, perfluorinated, compounds

本文参考文献

[1]

Shen H, Yu C, Ying Y, Zhao Y, Wu Y, Han J, Xu Q. Levels and congener profiles of PCDD/Fs, PCBs and PBDEs in seafood from China [J]. Chemosphere, 2009,77(9):1206-1211.

Shen H, Yu C, Ying Y, Zhao Y, Wu Y, Han J, Xu Q. Levels and congener profiles of PCDD/Fs, PCBs and PBDEs in seafood from China [J]. Chemosphere, 2009,77(9):1206-1211.

[2]

Sakurai T, Serizawa S, Isobe T, Kobayashi J, Kodama K, Kume G, Lee J H, Maki H, Imaizumi Y, Suzuki N, Horiguchi T, Morita M, Shiraishi H. Spatial, phase, and temporal distributions of perfluorooctane sulfonate (PFOS) and perfluorooctanoate (PFOA) in Tokyo Bay, Japan [J].Environmental Science & Technology, 2010,44(11):4110-4115.

Sakurai T, Serizawa S, Isobe T, Kobayashi J, Kodama K, Kume G, Lee J H, Maki H, Imaizumi Y, Suzuki N, Horiguchi T, Morita M, Shiraishi H. Spatial, phase, and temporal distributions of perfluorooctane sulfonate (PFOS) and perfluorooctanoate (PFOA) in Tokyo Bay, Japan [J].Environmental Science & Technology, 2010,44(11):4110-4115.

[3]

Dai J, Li M, Jin Y, Saito N, Xu M, Wei F. Perfluo-rooctanesulfonate and perfluorooctanoate in red panda and giant panda from China[J].Environmental Science & Technology, 2006,40(18):5647-5652.

Dai J, Li M, Jin Y, Saito N, Xu M, Wei F. Perfluo-rooctanesulfonate and perfluorooctanoate in red panda and giant panda from China[J].Environmental Science & Technology, 2006,40(18):5647-5652.

[4]

Kato K, Wong L Y, Jia L T, Kuklenyik Z, Calafat A M. Trends in exposure to polyfluoroalkyl chemicals in the U.S. population: 1999—2008 [J].Environmental Science & Technology, 2011,45(19):8037-8045.

Kato K, Wong L Y, Jia L T, Kuklenyik Z, Calafat A M. Trends in exposure to polyfluoroalkyl chemicals in the U.S. population: 1999—2008 [J].Environmental Science & Technology, 2011,45(19):8037-8045.

[5]

Yeung L W Y, So M K, Jiang G, Taniyasu S, Yamashita N, Song M, Wu Y, Li J, Giesy J P, Guruge K S, Lam P K S. Perfluorooctanesulfonate and related fluorochemicals in human blood samples from China [J].Environmental Science & Technology, 2005,40(3):715-720.

Yeung L W Y, So M K, Jiang G, Taniyasu S, Yamashita N, Song M, Wu Y, Li J, Giesy J P, Guruge K S, Lam P K S. Perfluorooctanesulfonate and related fluorochemicals in human blood samples from China [J].Environmental Science & Technology, 2005,40(3):715-720.

[6]

Kannan K. Perfluoroalkyl and polyfluoroalkyl substan-ces: Current and future perspectives [J].Environmental Chemistry, 2011,8(4):333-338.

Kannan K. Perfluoroalkyl and polyfluoroalkyl substan-ces: Current and future perspectives [J].Environmental Chemistry, 2011,8(4):333-338.

[7]

Dorneles P R, Lailson-Brito J, Azevedo A F, Meyer J, Vidal L G, Fragoso A B, Torres J P, Malm O, Blust R, Das K. High accumulation of perfluorooctane sulfonate (PFOS) in marine tucuxi dolphins (Sotalia guianensis) from the Brazilian coast [J].Environmental Science & Technology, 2008,42(14):5368-5373.

Dorneles P R, Lailson-Brito J, Azevedo A F, Meyer J, Vidal L G, Fragoso A B, Torres J P, Malm O, Blust R, Das K. High accumulation of perfluorooctane sulfonate (PFOS) in marine tucuxi dolphins (Sotalia guianensis) from the Brazilian coast [J].Environmental Science & Technology, 2008,42(14):5368-5373.

[8]

Loi E I H, Yeung L W Y, Taniyasu S, Lam P K S, Kannan K, Yamashita N. Trophic magnification of poly- and perfluorinated compounds in a subtropical food web [J].Environmental Science & Technology, 2011,45(13):5506-5513.

Loi E I H, Yeung L W Y, Taniyasu S, Lam P K S, Kannan K, Yamashita N. Trophic magnification of poly- and perfluorinated compounds in a subtropical food web [J].Environmental Science & Technology, 2011,45(13):5506-5513.

[9]

吴江平,管运涛,李明远,靳军涛,Yoshijima M,张锡辉.全氟化合物的生物富集效应研究进展[J].生态环境学报, 2010,19(5):1246-1252.

[10]

Li X, Yeung L W Y, Xu M, Taniyasu S, Lam P K S, Yamashita N, Dai J. Perfluorooctane sulfonate (PFOS) and other fluorochemicals in fish blood collected near the outfall of wastewater treatment plant (WWTP) in Beijing [J]. Environmental Pollution, 2008,156(3): 1298-1303.

Li X, Yeung L W Y, Xu M, Taniyasu S, Lam P K S, Yamashita N, Dai J. Perfluorooctane sulfonate (PFOS) and other fluorochemicals in fish blood collected near the outfall of wastewater treatment plant (WWTP) in Beijing [J]. Environmental Pollution, 2008,156(3): 1298-1303.

[11]

方雪梅,王建设,戴家银.全氟类有机污染物的污染状况及其生态毒理研究进展[J].地球科学进展, 2010,25(5):543-551.

[12]

Müller C E, De Silva A O, Small J, Williamson M, Wang X, Morris A, Katz S, Gamberg M, Muir D C G. Biomagnification of perfluorinated compounds in a remote terrestrial food chain: Lichen-caribou-wolf [J].Environmental Science & Technology, 2011,45(20):8665-8673.

Müller C E, De Silva A O, Small J, Williamson M, Wang X, Morris A, Katz S, Gamberg M, Muir D C G. Biomagnification of perfluorinated compounds in a remote terrestrial food chain: Lichen-caribou-wolf [J].Environmental Science & Technology, 2011,45(20):8665-8673.

[13]

Kärrman A, Harada K H, Inoue K, Takasuga T, Ohi E, Koizumi A. Relationship between dietary exposure and serum perfluorochemical (PFC) levels—A case study [J].Environment International, 2009, 35(4):712-717.

Kärrman A, Harada K H, Inoue K, Takasuga T, Ohi E, Koizumi A. Relationship between dietary exposure and serum perfluorochemical (PFC) levels—A case study [J].Environment International, 2009, 35(4):712-717.

[14]

Yamashita N, Kannan K, Taniyasu S, Horii Y, Petrick G, Gamo T. A global survey of perfluorinated acids in oceans [J].Marine Pollution Bulletin,2005,51(8-12):658-668.

Yamashita N, Kannan K, Taniyasu S, Horii Y, Petrick G, Gamo T. A global survey of perfluorinated acids in oceans [J].Marine Pollution Bulletin,2005,51(8-12):658-668.

[15]

Yamashita N, Taniyasu S, Petrick G, Wei S, Gamo T, Lam P K S, Kannan K. Perfluorinated acids as novel chemical tracers of global circulation of ocean waters [J].Chemosphere, 2008,70(7):1247-1255.

Yamashita N, Taniyasu S, Petrick G, Wei S, Gamo T, Lam P K S, Kannan K. Perfluorinated acids as novel chemical tracers of global circulation of ocean waters [J].Chemosphere, 2008,70(7):1247-1255.

[16]

Young C J, Furdui V I, Franklin J, Koerner R M, Muir D C G, Mabury S A. Perfluorinated acids in arctic snow: New evidence for atmospheric formation [J].Environmental Science & Technology, 2007,41(10):3455-3461.

Young C J, Furdui V I, Franklin J, Koerner R M, Muir D C G, Mabury S A. Perfluorinated acids in arctic snow: New evidence for atmospheric formation [J].Environmental Science & Technology, 2007,41(10):3455-3461.

[17]

Giesy J P, Kannan K. Global distribution of perfluoro-octane sulfonate in wildlife [J].Environmental Science & Technology, 2001,35(7):1339-1342.

Giesy J P, Kannan K. Global distribution of perfluoro-octane sulfonate in wildlife [J].Environmental Science & Technology, 2001,35(7):1339-1342.

[18]

Zhang L, Liu J, Hu J, Liu C, Guo W, Wang Q, Wang H . The inventory of sources, environmental releases and risk assessment for perfluorooctane sulfonate in China [J].Environmental Pollution (in press).

Zhang L, Liu J, Hu J, Liu C, Guo W, Wang Q, Wang H . The inventory of sources, environmental releases and risk assessment for perfluorooctane sulfonate in China [J].Environmental Pollution (in press).

[19]

Lu G H, Yang Y L, Taniyasu S, Yeung L W Y, Pan J, Zhou B, Lam P K S, Yamashita N. Potential exposure of perfluorinated compounds to Chinese in Shenyang and Yangtze River Delta areas [J].Environmental Chemistry, 2011,8(4):407-418.

Lu G H, Yang Y L, Taniyasu S, Yeung L W Y, Pan J, Zhou B, Lam P K S, Yamashita N. Potential exposure of perfluorinated compounds to Chinese in Shenyang and Yangtze River Delta areas [J].Environmental Chemistry, 2011,8(4):407-418.

[20]

Yang L, Zhu L, Liu Z. Occurrence and partition of per-fluorinated compounds in water and sediment from Liao River and Taihu Lake, China [J].Chemosphere, 2011,83(6):806-814.

Yang L, Zhu L, Liu Z. Occurrence and partition of per-fluorinated compounds in water and sediment from Liao River and Taihu Lake, China [J].Chemosphere, 2011,83(6):806-814.

[21]

So M K, Miyake Y, Yeung W Y, Ho Y M, Taniyasu S, Rostkowski P, Yamashita N, Zhou B S, Shi X J, Wang J X, Giesy J P, Yu H, Lam P K S. Perfluorinated compounds in the Pearl River and Yangtze River of China [J].Chemosphere, 2007,68(11):2085-2095.

So M K, Miyake Y, Yeung W Y, Ho Y M, Taniyasu S, Rostkowski P, Yamashita N, Zhou B S, Shi X J, Wang J X, Giesy J P, Yu H, Lam P K S. Perfluorinated compounds in the Pearl River and Yangtze River of China [J].Chemosphere, 2007,68(11):2085-2095.

[22]

Qiu Y, Jing H, Shi H. Perfluorocarboxylic acids (PFCAs) and perfluoroalkyl sulfonates (PFASs) in surface and tap water around Lake Taihu in China [J].Frontiers of Environmental Science & Engineering in China, 2010,4(3):301-310.

Qiu Y, Jing H, Shi H. Perfluorocarboxylic acids (PFCAs) and perfluoroalkyl sulfonates (PFASs) in surface and tap water around Lake Taihu in China [J].Frontiers of Environmental Science & Engineering in China, 2010,4(3):301-310.

[23]

Wang T, Lu Y, Chen C, Naile J, Khim J, Giesy J. Perfluorinated compounds in a coastal industrial area of Tianjin, China [J].Environmental Geochemistry and Health (in press).

Wang T, Lu Y, Chen C, Naile J, Khim J, Giesy J. Perfluorinated compounds in a coastal industrial area of Tianjin, China [J].Environmental Geochemistry and Health (in press).

[24]

Li F, Sun H, Hao Z, He N, Zhao L, Zhang T, Sun T. Perfluorinated compounds in Haihe River and Dagu Drainage Canal in Tianjin, China [J].Chemosphere, 2011,84(2):265-271.

Li F, Sun H, Hao Z, He N, Zhao L, Zhang T, Sun T. Perfluorinated compounds in Haihe River and Dagu Drainage Canal in Tianjin, China [J].Chemosphere, 2011,84(2):265-271.

[25]

Wang T, Chen C, Naile J, Khim J, Giesy J, Lu Y. Perfluorinated compounds in water, sediment and soil from Guanting Reservoir, China [J].Bulletin of Environmental Contamination and Toxicology, 2011,87(1):74-79.

Wang T, Chen C, Naile J, Khim J, Giesy J, Lu Y. Perfluorinated compounds in water, sediment and soil from Guanting Reservoir, China [J].Bulletin of Environmental Contamination and Toxicology, 2011,87(1):74-79.

[26]

Mak Y L, Taniyasu S, Yeung L W Y, Lu G, Jin L, Yang Y, Lam P K S, Kannan K, Yamashita N. Perfluorinated compounds in tap water from China and several other countries [J].Environmental Science & Technology, 2009,43(13):4824-4829.

Mak Y L, Taniyasu S, Yeung L W Y, Lu G, Jin L, Yang Y, Lam P K S, Kannan K, Yamashita N. Perfluorinated compounds in tap water from China and several other countries [J].Environmental Science & Technology, 2009,43(13):4824-4829.

[27]

Wang T, Khim J S, Chen C, Naile J E, Lu Y, Kannan K , Park J, Luo W, Jiao W, Hu W, Giesy J P. Perfluorinated compounds in surface waters from Northern China: Comparison to level of industrialization [J].Environment International (in press).

Wang T, Khim J S, Chen C, Naile J E, Lu Y, Kannan K , Park J, Luo W, Jiao W, Hu W, Giesy J P. Perfluorinated compounds in surface waters from Northern China: Comparison to level of industrialization [J].Environment International (in press).

[28]

Kwok K Y, Taniyasu S, Yeung L W Y, Murphy M B, Lam P K S, Horii Y, Kannan K, Petrick G, Sinha R K, Yamashita N. Flux of perfluorinated chemicals through wet deposition in Japan, the United States, and several other countries [J].Environmental Science & Technology, 2010,44(18):7043-7049.

Kwok K Y, Taniyasu S, Yeung L W Y, Murphy M B, Lam P K S, Horii Y, Kannan K, Petrick G, Sinha R K, Yamashita N. Flux of perfluorinated chemicals through wet deposition in Japan, the United States, and several other countries [J].Environmental Science & Technology, 2010,44(18):7043-7049.

[29]

Taniyasu S, Kannan K, So M K, Gulkowska A, Sinclair E , Okazawa T, Yamashita N. Analysis of fluorotelomer alcohols, fluorotelomer acids, and short- and long-chain perfluorinated acids in water and biota [J].Journal of Chromatography A, 2005,1093(1-2):89-97.

Taniyasu S, Kannan K, So M K, Gulkowska A, Sinclair E , Okazawa T, Yamashita N. Analysis of fluorotelomer alcohols, fluorotelomer acids, and short- and long-chain perfluorinated acids in water and biota [J].Journal of Chromatography A, 2005,1093(1-2):89-97.

[30]

Müller C E, Spiess N, Gerecke A C, Scheringer M, Hungerbühler K. Quantifying diffuse and point inputs of perfluoroalkyl acids in a nonindustrial river catchment [J].Environmental Science & Technology, 2011.

Müller C E, Spiess N, Gerecke A C, Scheringer M, Hungerbühler K. Quantifying diffuse and point inputs of perfluoroalkyl acids in a nonindustrial river catchment [J].Environmental Science & Technology, 2011.

[31]

Müller C E, Gerecke A C, Alder A C, Scheringer M, Hungerbühler K. Identification of perfluoroalkyl acid sources in Swiss surface waters with the help of the artificial sweetener acesulfame [J].Environmental Pollution, 2011,159(5):1419-1426.

Müller C E, Gerecke A C, Alder A C, Scheringer M, Hungerbühler K. Identification of perfluoroalkyl acid sources in Swiss surface waters with the help of the artificial sweetener acesulfame [J].Environmental Pollution, 2011,159(5):1419-1426.

[32]

Dinglasan M J A, Ye Y, Edwards E A, Mabury S A. Fluorotelomer alcohol biodegradation yields poly- and perfluorinated acids [J].Environmental Science & Technology, 2004,38(10):2857-2864.

Dinglasan M J A, Ye Y, Edwards E A, Mabury S A. Fluorotelomer alcohol biodegradation yields poly- and perfluorinated acids [J].Environmental Science & Technology, 2004,38(10):2857-2864.

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[1]

地下水氟含量测定及测定影响因素研究[J]. 孙义,曾玉香.  广西科学. 2013(02)

[2]

典型城市河道全氟化合物环境暴露水平及植物富集特征[D]. 蒋曌泽.牡丹江师范学院 2015

[3]

大运河丰水期水体中全氟化合物的分布[J]. 朴海涛,陈舒,焦杏春,盖楠,殷效彩,路国慧,王晓春,谭科艳,潘静,杨永亮.  中国环境科学. 2016(10)

[4]

典型全氟化合物对大型蚤和斑马鱼生态毒理影响初步研究[D]. 杨杰频.河北科技大学 2014

[5]

中国东部地区典型全氟化合物污染地理分布特征及来源辨析[D]. 陈舒.中国地质科学院 2016

[6]

固相萃取-超高效液相色谱/串联质谱法测定人体血清中7种全氟化合物[J]. 肖永华,梁高道,革丽亚,黄常刚,王胜,麦琦.  分析科学学报. 2015(05)

[7]

固相萃取-液相色谱/质谱法测定地下水中三嗪类和酰胺类除草剂残留[J]. 左海英,张琳,刘菲.  岩矿测试. 2014(01)

[8]

纺织品中全氟化合物检测技术研究现状[J]. 刘葳,张增强.  化纤与纺织技术. 2016(01)

[9]

浑河—大辽河水系水体和沉积物中典型全氟化合物的污染现状及吸附特性研究[D]. 巩秀贤.山东理工大学 2015

[10]

全氟辛烷磺酸盐和全氟辛酸在水环境及水生生物体内积累的研究进展[J]. 黄楚珊,张丽娟,胡国成,李良忠,陈棉彪.  环境科技. 2014(05)

[11]

超高效液相色谱-串联质谱法测定蔬菜中15种全氟化合物[J]. 赵玉乐,朱冬雪,黄宝勇,肖志勇,杨红菊,何沛桥,赵源,唐晓菲.  农产品质量与安全. 2017(03)

[12]

全氟辛烷磺酸对大型蚤的慢性毒性研究[J]. 沈洪艳,杨杰频,曹志会,王冰,赵月.  河北科技大学学报. 2014(04)

[13]

高效液相色谱-串联质谱法在全氟化合物检测中的应用[J]. 徐睿,谭红,何锦林,张运依.  贵州科学. 2015(01)

[14]

双台子河口水体全氟化合物的污染水平分析[J]. 魏立娥,邵秘华,张晶,魏媛媛,李扬,丁光辉.  环境科学学报. 2016(05)

[15]

食品接触材料中PFCs的检测及迁移规律研究[D]. 徐睿.贵州大学 2015

[16]

双台子河口水体全氟化合物污染分布及风险评估研究[D]. 魏立娥.大连海事大学 2015

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高效液相色谱-串联质谱法测定黄河河口段水中全氟化合物的初步研究

路国慧, 沈亚婷, 何俊, 袁帆, 杨永亮, 饶竹