【引用本文】 袁继海, 詹秀春, 樊兴涛, 等. 硫化物矿物中痕量元素的激光剥蚀-电感耦合等离子体质谱微区分析进展[J]. 岩矿测试, 2011, 30(2): 121-130.
 ,  ,  , et al. Development of Microanalysis of Trace Elements in Sulfide Minerals by Laser Ablation-Inductively Coupled Plasma-Mass Spectrometry[J]. Rock and Mineral Analysis, 2011, 30(2): 121-130.

硫化物矿物中痕量元素的激光剥蚀-电感耦合等离子体质谱微区分析进展

1. 

国家地质实验测试中心, 北京 100037

2. 

国家地质实验测试中心, 北京 100037

3. 

国家地质实验测试中心, 北京 100037

4. 

国家地质实验测试中心, 北京 100037

收稿日期: 2010-10-19  修回日期: 2010-12-12 

基金项目: 科技部创新方法工作专项资助(2009IM032200)

Development of Microanalysis of Trace Elements in Sulfide Minerals by Laser Ablation-Inductively Coupled Plasma-Mass Spectrometry

1. 

National Research Center for Geoanalysis, Beijing 100037, China

2. 

National Research Center for Geoanalysis, Beijing 100037, China

3. 

National Research Center for Geoanalysis, Beijing 100037, China

4. 

National Research Center for Geoanalysis, Beijing 100037, China

Received Date: 2010-10-19
Revised Date: 2010-12-12

摘要:第一行过渡金属元素及痕量贵金属元素高度富集在硫化物矿物中,常形成具有工业意义的矿床,使得硫化物具有重大的经济价值。对天然硫化物矿物中的这些痕量金属元素丰度及其分布的研究,在矿石成因学、经济地质学、环境地球化学等领域具有重要的应用价值。激光剥蚀-电感耦合等离子体质谱(LA-ICP-MS)微区分析技术是一种强大的痕量元素分析工具,非常适合直接分析硫化物矿物中痕量元素的浓度及其空间分布。由于硫化物的激光剥蚀特性与硅酸盐及氧化物不同,分析校准用的标准物质又极度缺乏,严重阻碍了这一技术在硫化物矿物微区分析中的应用。本文评述了硫化物简介、硫化物中痕量金属元素分析的意义、LA-ICP-MS微区分析技术在硫化物矿物痕量元素分析中的优势及近年来的应用进展、硫化物分析中的干扰与校准、包含铂族元素及金的硫化物标准物质的研制进展及合成硫化物标准物质最有应用前景的方法。

关键词: 硫化物矿物, 激光剥蚀-电感耦合等离子体质谱法, 微区分析, 痕量元素, 标准物质

Development of Microanalysis of Trace Elements in Sulfide Minerals by Laser Ablation-Inductively Coupled Plasma-Mass Spectrometry

KEY WORDS: sulfide, mineral, laser, ablation-inductively, coupled

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硫化物矿物中痕量元素的激光剥蚀-电感耦合等离子体质谱微区分析进展

袁继海, 詹秀春, 樊兴涛, 胡明月