【引用本文】 佟 玲, 吴淑琪, 杨佳佳, 等. 土壤中25种有机氯农药和多氯联苯的气相色谱分析方法研究[J]. 岩矿测试, 2010, 29(3): 277-281.
 ,  ,  , et al. Determination of 25 Organochlorine Pesticides and Polychlorinated Biphenyls in Soils by Gas Chromatography[J]. Rock and Mineral Analysis, 2010, 29(3): 277-281.

土壤中25种有机氯农药和多氯联苯的气相色谱分析方法研究

1. 

国家地质实验测试中心, 北京 100037

2. 

国家地质实验测试中心, 北京 100037

3. 

国家地质实验测试中心, 北京 100037

4. 

国家地质实验测试中心, 北京 100037

收稿日期: 2009-07-08  修回日期: 2010-02-25 

基金项目: 国土资源地质大调查工作项目资助(1212010816028)

Determination of 25 Organochlorine Pesticides and Polychlorinated Biphenyls in Soils by Gas Chromatography

1. 

National Research Center for Geoanalysis, Beijing 100037, China

2. 

National Research Center for Geoanalysis, Beijing 100037, China

3. 

National Research Center for Geoanalysis, Beijing 100037, China

4. 

National Research Center for Geoanalysis, Beijing 100037, China

Received Date: 2009-07-08
Revised Date: 2010-02-25

摘要:研究了土壤中17种有机氯农药和8种多氯联苯组分的气相色谱分析方法。采用加速溶剂萃取技术提取,优化了萃取条件。提取液用固相萃取技术进行净化,采用20 mL含3%(体积分数)甲苯的正己烷-乙酸乙酯(体积比82)进行淋洗,得到很好的净化效果。方法检出限在0.06~0.27 μg/kg,线性范围在1.38~55.2 ng/mL,目标化合物的平均添加回收率在65%~97%,相对标准偏差(RSD,n=6)小于17.11%。方法快速、灵敏、准确,适合批量样品的分析。

关键词: 土壤, 有机氯农药, 多氯联苯, 加速溶剂萃取, 气相色谱法

Determination of 25 Organochlorine Pesticides and Polychlorinated Biphenyls in Soils by Gas Chromatography

KEY WORDS: soil, organochlorine, pesticides, polychlorinated, biphenyls

本文参考文献

[1]

赵玲,马永军.有机氯农药残留对土壤环境的影响[J].土壤,2001(6):309-311.

[2]

李政禹.国际上持久性有机污染物的控制动向及其对策[J].现代化工,1999,19(7):5-8.

[3]

Li H P, Li G C, Jen J F. Determination of organochlorine pesticides in water using microwave assisted headspace solid-phase microextraction and gas chromatography [J].Journal of Chromatography A,2003,1012:129-137.

Li H P, Li G C, Jen J F. Determination of organochlorine pesticides in water using microwave assisted headspace solid-phase microextraction and gas chromatography [J].Journal of Chromatography A,2003,1012:129-137.

[4]

Westbom R, Th rneby L, Zorita S, Mathiasson L, Bjrklund E. Development of a solid-phase extraction method for the determination of polychlorinated biphenyls in water [J].Journal of Chromatography A,2004,1033:1-8.

Westbom R, Th rneby L, Zorita S, Mathiasson L, Bjrklund E. Development of a solid-phase extraction method for the determination of polychlorinated biphenyls in water [J].Journal of Chromatography A,2004,1033:1-8.

[5]

Fatoki O S, Awofolu R O. Methods for selective determination of persistent organochlorine pesticide residues in water and sediments by capillary gas chromatography and electron-capture detection [J].Journal of Chromatography A,2003,983:225-236.

Fatoki O S, Awofolu R O. Methods for selective determination of persistent organochlorine pesticide residues in water and sediments by capillary gas chromatography and electron-capture detection [J].Journal of Chromatography A,2003,983:225-236.

[6]

US EPA Method 8081A. Organochlorine pesticides by gas chromatography[S].

US EPA Method 8081A. Organochlorine pesticides by gas chromatography[S].

[7]

佟玲,黄园英,张玲金,吴淑琪.土壤中持久性有机污染物分析的前处理方法[J].岩矿测试,2008,27(2):81-86.

[8]

王芳,蒋新,赵振华,汪立刚,卞永荣,郜红建.土壤中有机氯农药的多残留分析技术[J].环境化学,2004,23(5):591-595.

[9]

Doong R A, Liao P L. Determination of organochlorine pesticides and their metabolites in soil samples using headspace solid-phase microextraction [J].Journal of Chromatography A,2001,918:177-188.

Doong R A, Liao P L. Determination of organochlorine pesticides and their metabolites in soil samples using headspace solid-phase microextraction [J].Journal of Chromatography A,2001,918:177-188.

[10]

郜红建,蒋新,常江.加速溶剂提取-气相色谱法测定蔬菜中的有机氯农药[J].生态环境,2007,16(1):50-53.

[11]

申中兰,蔡继宝,高芸,朱晓兰,苏庆德.基质固相分散-加速溶剂萃取-气相色谱法测土壤中有机氯农药残留[J].分析化学,2005,33(9):1318-1320.

[12]

江奎,汪雨,支辛辛,杨永亮,张玲金.加速溶剂萃取/GC-ECD分析土壤中多氯联苯的研究[J].青岛大学学报,2006,21(1):18-21.

[13]

Saito K, Sjodin A, Sandau C D, Davis M D, Nakazawa H, Matsuki Y, Patterson Jr D G. Development of an accelerated solvent extraction and gel permeation chromatography analytical method for measuring persistent organohalogen compounds in adipose and organ tissue analysis [J].Chemosphere,2004,57:373-381.

Saito K, Sjodin A, Sandau C D, Davis M D, Nakazawa H, Matsuki Y, Patterson Jr D G. Development of an accelerated solvent extraction and gel permeation chromatography analytical method for measuring persistent organohalogen compounds in adipose and organ tissue analysis [J].Chemosphere,2004,57:373-381.

[14]

Yusa V, Quintas G, Pardo O, Pastor A, Guardia M D L. Determination of PAHs in airborne particles by accelerated solvent extraction and large-volume injection-gas chromatography-mass spectrometry [J].Talanta,2006,69:807-815.

Yusa V, Quintas G, Pardo O, Pastor A, Guardia M D L. Determination of PAHs in airborne particles by accelerated solvent extraction and large-volume injection-gas chromatography-mass spectrometry [J].Talanta,2006,69:807-815.

[15]

杨丽丽.有机氯农药的固相萃取前处理技术和分析方法[J].北京工业大学学报,2003,29(1):68-72.

[16]

Jank K, Jensenb E, Becherb G. Determination of polychlorinated biphenyls in human blood by solid-phase extraction including on-column lipid decom-position [J].Journal of Chromatography B,1999,734:219-227.

Jank K, Jensenb E, Becherb G. Determination of polychlorinated biphenyls in human blood by solid-phase extraction including on-column lipid decom-position [J].Journal of Chromatography B,1999,734:219-227.

[17]

Barwick V J, Ellison S L R, Lacey S J, Mussell C R, Lucking C L. Evaluation of a solid phase extraction procedure for the determination of pesticide residues in foodstuffs [J].Journal of the Science of Food and Agriculture,1999,79:1190-1196.

Barwick V J, Ellison S L R, Lacey S J, Mussell C R, Lucking C L. Evaluation of a solid phase extraction procedure for the determination of pesticide residues in foodstuffs [J].Journal of the Science of Food and Agriculture,1999,79:1190-1196.

[18]

US EPA Method 508. Determination of chlorinated pesticides in water by gas chromatography with an electron capture detector[S].

US EPA Method 508. Determination of chlorinated pesticides in water by gas chromatography with an electron capture detector[S].

相似文献(共20条)

[1]

黄园英, 吴淑琪, 佟玲, 张玲金. 土壤中持久性有机污染物分析的前处理方法. 岩矿测试, 2008, 27(2): 81-86.

[2]

饶竹, 何淼. 圆盘固相萃取富集-气相色谱法测定地表水中有机氯和有机磷农药. 岩矿测试, 2008, 27(1): 12-16.

[3]

张岩, 张景发, 陈艳梅, 孟娟, 韩翠英. 加速溶剂萃取-气相色谱法测定土壤中有机氯农药和多氯联苯. 岩矿测试, 2010, 29(5): 491-496.

[4]

杨佳佳, 佟玲, 吴淑琪, 阎妮. 加速溶剂萃取-气相色谱法测定谷物中有机氯农药和多氯联苯. 岩矿测试, 2013, 32(3): 487-494.

[5]

陈卫明, 李庆霞, 张芳, 何小辉, 张勤. 加速溶剂萃取-气相色谱/气相色谱-质谱法测定土壤中7种多氯联苯. 岩矿测试, 2011, 30(1): 33-39.

[6]

魏峰, 沈小明, 陈海英, 沈加林. 土壤和沉积物中22种有机氯农药和8种多氯联苯的气相色谱分析. 岩矿测试, 2013, 32(6): 952-958.

[7]

刘广民, 尹莉莉, 董永亮, 肖宇芳. 土壤中五氯酚的快速测定. 岩矿测试, 2008, 27(2): 117-119.

[8]

饶竹, 何淼, 陈巍, 李松, 刘艳. 土壤样品中有机磷农药的加速溶剂萃取-气相色谱测定. 岩矿测试, 2010, 29(5): 503-507.

[9]

佟玲, 杨佳佳, 阎妮, 吴淑琪. 加速溶剂提取/GC-MS同时测定动物组织中有机氯农药和多氯联苯. 岩矿测试, 2014, 33(2): 262-269.

[10]

肖刚. 加速溶剂提取-气相色谱法同时测定土壤中的22种有机氯和有机磷农药. 岩矿测试, 2012, 31(6): 1033-1036.

[11]

马晗宇, 刘菲, 刘玉龙. 气相色谱法测定地下水中有机氯农药和多氯联苯. 岩矿测试, 2010, 29(5): 527-530.

[12]

方金梅. 福州市土壤硒形态分析及其迁移富集规律. 岩矿测试, 2008, 27(2): 103-107.

[13]

田芹, 吴淑琪, 佟玲, 罗代洪. 中国典型类型土壤中有机氯农药和多氯联苯成分分析标准物质的研制. 岩矿测试, 2015, 34(2): 238-244. doi: 10.15898/j.cnki.11-2131/td.2015.02.015

[14]

江林, 刘晓端, 张静. 土壤中不同形态砷的分析方法. 岩矿测试, 2008, 27(3): 179-183.

[15]

宋淑玲, 饶竹, 李松. 全国地下水调查中12种半挥发性必检组分的测定. 岩矿测试, 2008, 27(2): 91-94.

[16]

薛源, 杨永亮, 万奎元, 吴学丽, 朱晓华, 王晓春, 罗松光. 沈阳市细河周边农田土壤和大气中有机氯农药和多氯联苯初步研究. 岩矿测试, 2011, 30(1): 27-32.

[17]

齐璐璐, 赵会芹, 陈子学, 郑育锁, 孟凡辉, 肖波, 张颖. 连续光源原子吸收光谱法测定土壤水溶性盐中钙镁. 岩矿测试, 2008, 27(2): 95-98.

[18]

周涛, 韩彬, 徐亚岩, 刘新民, 郑立, 王小如. 南中国海海水中有机氯农药和多氯联苯的含量及分布特征. 岩矿测试, 2014, 33(1): 90-95.

[19]

孙青, 李松. 高压气相色谱法快速测定痕量长链烯酮. 岩矿测试, 2008, 27(1): 5-8.

[20]

曹孝文, 邹宽, 徐丹, 沈伟健, 练鸿振, 葛欣, 沈崇钰. 食品中有机氯农药和多氯联苯气相色谱-质谱分析的离子化方式. 岩矿测试, 2013, 32(1): 22-27.

计量
  • PDF下载量(1023)
  • 文章访问量(1340)
  • 被引次数(0)
目录

Figures And Tables

土壤中25种有机氯农药和多氯联苯的气相色谱分析方法研究

佟 玲, 吴淑琪, 杨佳佳, 张玲金