【引用本文】 高梓涵, 李立武, 王玉慧, 等. 一种双真空炉管的研制及其在岩石加热脱气气体组分测试中的应用[J]. 岩矿测试, 2019, 38(5): 469-478. doi: 10.15898/j.cnki.11-2131/td.201812190138
GAO Zi-han , LI Li-wu , WANG Yu-hui , et al. Development of a Double Vacuum Furnace Tube and Its Application in Gas Composition Determination during Rock Heating Degassing[J]. Rock and Mineral Analysis, 2019, 38(5): 469-478. doi: 10.15898/j.cnki.11-2131/td.201812190138

一种双真空炉管的研制及其在岩石加热脱气气体组分测试中的应用

1. 中国科学院西北生态环境资源研究院, 甘肃 兰州 730000;

2. 甘肃省油气资源研究重点实验室/中国科学院油气资源研究重点实验室, 甘肃 兰州 730000;

3. 中国科学院大学, 北京 100049

收稿日期: 2018-12-19  修回日期: 2019-05-14 

基金项目: 国家自然科学基金资助项目(41473062)

作者简介: 高梓涵,硕士研究生,地质工程专业。E-mail:2810652521@qq.com。。

Development of a Double Vacuum Furnace Tube and Its Application in Gas Composition Determination during Rock Heating Degassing

1. Northwest Institute of Eco-Environment and Resources, Chinese Academy of Sciences, Lanzhou 730000, China;

2. Key Laboratory of Petroleum Resources, Gansu Province/Key Laboratory of Petroleum Resources Research, Chinese Academy of Sciences, Lanzhou 730000, China;

3. University of Chinese Academy of Sciences, Beijing 100049, China

Received Date: 2018-12-19
Revised Date: 2019-05-14

摘要:分析岩石矿物中的气体化学组成,可为岩石圈地幔的不同地球化学过程、地球内部氧化还原环境以及水在深部地球中的循环等研究提供重要的信息与约束条件。对岩矿样品加热使气体脱出是一种常用的实验手段,使用单石英玻璃管作为样品管,石英玻璃结构中不规则的空隙使得气体在高温下易发生扩散与渗透;由钼、钽坩埚组成的双真空炉管一般用于稀有气体同位素组成分析,较少见于用于气体化学组成分析,且该装置结构复杂,不易组装拆解,也易被损坏。针对以上问题,本文研制了石英玻璃与金属零件组成的双真空盛样炉管,该炉管具有体积小、易于组装、拆解和移动等特点。在相同的实验条件下与单石英玻璃管进行对照实验。根据实验结果,尤其是H2浓度的测量结果表明:不论哪种类型的样品在500℃和950℃加热脱气时,应用本文研制的双真空盛样炉管,测量的H2浓度均高于同等实验条件下应用单石英玻璃管测量的H2浓度,该双真空炉管的气密性优于单石英玻璃管,有利于获得样品中更加真实的气体化学组成。

关键词: 双真空炉管, 单石英玻璃管, 气相色谱法, 岩石脱气

Development of a Double Vacuum Furnace Tube and Its Application in Gas Composition Determination during Rock Heating Degassing

KEY WORDS: fluid inclusions, double-vacuum furnace sample-tube, gas chromatography, gas-released from rock

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一种双真空炉管的研制及其在岩石加热脱气气体组分测试中的应用

高梓涵, 李立武, 王玉慧, 曹春辉, 贺坚