【引用本文】 赵志飞, 任小荣, 李策, 等. 氧气反应模式-电感耦合等离子体串联质谱法测定土壤中的镉[J]. 岩矿测试, 2021, 40(1): 103-110. doi: 10.15898/j.cnki.11-2131/td.202003150034
ZHAO Zhi-fei , REN Xiao-rong , LI Ce , et al. Determination of Cadmium in Soil Samples by ICP-MS/MS Using Oxygen Reaction Mode[J]. Rock and Mineral Analysis, 2021, 40(1): 103-110. doi: 10.15898/j.cnki.11-2131/td.202003150034

氧气反应模式-电感耦合等离子体串联质谱法测定土壤中的镉

1. 安捷伦科技(中国)有限公司, 北京 100102;

2. 湖北省地质实验测试中心, 湖北 武汉 430022;

3. 中国科学院南京土壤研究所, 江苏 南京 210000

收稿日期: 2020-03-15  修回日期: 2020-04-17 

作者简介: 赵志飞,硕士,应用工程师,从事原子光谱方法开发研究。E-mail:zzfeel@126.com。。

Determination of Cadmium in Soil Samples by ICP-MS/MS Using Oxygen Reaction Mode

1. Agilent Technologies(China) Co., LTD, Beijing 100102, China;

2. Hubei Geological Research Laboratory, Wuhan 430022, China;

3. Institute of Soil Science, Chinese Academy of Sciences, Nanjing 210000, China

Received Date: 2020-03-15
Revised Date: 2020-04-17

摘要:应用电感耦合等离子体质谱法(ICP-MS)分析土壤中的镉元素时,锆的氢氧化物、钼的氧化物、锡的同位素会对镉造成严重的干扰,导致土壤中镉的准确测定难度较大。本文采用电感耦合等离子体串接质谱法(ICP-MS/MS),选取无同质异位素干扰的111Cd为分析谱线,在MS/MS模式下碰撞反应池中通入的氧气可以与94Zr16O1H+95Mo16O+进行电子转移、去氢、加氧等反应,抑制这些多原子离子对111Cd+的重叠干扰。结果表明:氧气流量越大,去除多原子离子的效果越好,当氧气流量在0.45mL/min时,溶液中2000μg/L以下的锆、1000 μg/L以下的钼在111Cd处形成的多原子重叠干扰小于0.005μg/L。实验在石墨消解仪中采用氢氟酸-硝酸-高氯酸消解样品,盐酸复溶,溶液定容稀释至1000倍测定,方法检出限(3δ)达到0.003μg/g;本方法经过国家土壤一级标准物质验证,11个国家土壤一级标准物质的测量值和认定值的相对误差在±7%以内,3个国家土壤一级标准物质精密度(RSD,n=12)小于5%。本方法可以作为土壤样品中痕量镉元素的方法使用。

关键词: 土壤, , 氧气反应模式, 多原子离子, 电感耦合等离子体串接质谱法

Determination of Cadmium in Soil Samples by ICP-MS/MS Using Oxygen Reaction Mode

KEY WORDS: soil, cadmium, oxygen reaction mode, polyatomic ion, triple quadrupole inductively coupled plasma-mass spectrometry

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氧气反应模式-电感耦合等离子体串联质谱法测定土壤中的镉

赵志飞, 任小荣, 李策, 郭朝, 宋娟娥, 龚华