铁锰矿物-生物炭协同固定水中硝酸盐的机制与应用进展

Mechanisms and Application Advances in the Synergistic Immobilization of Nitrate by Iron-Manganese Minerals and Biochar in Water

  • 摘要: 水环境硝酸盐污染对生态系统安全和人体健康构成严重威胁。现有修复技术普遍存在成本高、易产生二次污染等局限,亟需开发高效、可持续的硝酸盐治理途径。铁锰矿物-生物炭协同固定技术通过多机制耦合作用,能够显著提升硝酸盐的去除效率,已成为水污染控制领域的研究热点。本文系统评述了铁锰矿物-生物炭复合材料的协同作用机制,涵盖表面吸附、氧化还原、配体交换和静电吸引等关键过程;分析了温度、pH、材料投加量、金属比例及共存离子等因素对固定效果的协同影响:温度升高通常促进吸附动力学与容量;酸性条件利于材料表面质子化,增强静电吸引;投加量需权衡总去除率与单位吸附效率;Fe/Mn等金属比例的优化可调控活性位点分布与反应路径;共存离子则通过竞争吸附或电荷调节产生复杂干扰。这些因素相互关联,共同决定了复合材料在实际水体中的适配性与效能。本文进一步评估了该技术在实际水体修复中的应用潜力与现存局限。已有研究表明,铁锰矿物-生物炭协同体系在硝酸盐去除方面具有高效、稳定和环境友好等优势,但仍面临实际水体适应性不足、材料制备缺乏标准化以及长期稳定性不确定等挑战。建议未来研究应致力于材料构建策略的优化、反应机理的深入解析,并积极推进工程应用示范,为实现硝酸盐污染的高效与可持续治理提供理论依据与技术方案。

     

    Abstract: Nitrate pollution in water environment poses a serious threat to ecosystem security and human health. The existing remediation technologies generally have the limitations of high cost and easy to produce secondary pollution. It is urgent to develop efficient and sustainable nitrate treatment methods. The synergistic immobilization technology of iron-manganese minerals and biochar can significantly improve the removal efficiency of nitrate through multi-mechanism coupling, which has become a research hotspot in the field of water pollution control. This paper systematically reviews the synergistic mechanism of iron-manganese minerals and biochar composites, covering key processes such as surface adsorption, redox, ligand exchange and electrostatic attraction. The synergistic effects of temperature, pH, material dosage, metal ratio and coexisting ions on the immobilization effect were analyzed. The increase of temperature usually promoted the adsorption kinetics and capacity. Acidic conditions are conducive to the protonation of the material surface and enhance electrostatic attraction; the dosage needs to weigh the total removal rate and the unit adsorption efficiency; the optimization of metal ratios such as Fe/Mn can regulate the distribution of active sites and the reaction path. The coexisting ions produce complex interference through competitive adsorption or charge regulation. These factors are interrelated and jointly determine the suitability and effectiveness of the composite material in the actual water body. This paper further evaluates the application potential and existing limitations of this technology in actual water body restoration. Studies have shown that the iron-manganese mineral-biochar synergistic system has the advantages of high efficiency, stability and environmental friendliness in nitrate removal, but it still faces challenges such as insufficient adaptability to actual water bodies, lack of standardization in material preparation, and uncertainty in long-term stability. It is suggested that future research should focus on the optimization of material construction strategy, the in-depth analysis of reaction mechanism, and actively promote the demonstration of engineering application, so as to provide theoretical basis and technical scheme for the efficient and sustainable treatment of nitrate pollution.

     

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