青海共和盆地塔秀滩富锶地下水分布特征及形成机制研究

Distribution Characteristics and Formation Mechanism of Strontium-Enriched Groundwater in the Taxiutan of Gonghe Basin, Qinghai Province

  • 摘要: 青海省蕴藏着丰富的优质天然矿泉水资源,尤以富锶矿泉水为特色。然而,前人研究多集中于岩溶区富锶水体,对松散岩类孔隙型富锶地下水的水化学特征、锶元素空间分异规律及富集机理的认识仍显不足。为此,本文以青海共和盆地塔秀滩为研究区,采集156组水样与38组岩土样,综合运用Piper三线图、Pearson相关性分析、主成分分析(PCA)及空间插值等方法,系统揭示了松散岩类地区富锶地下水的水化学特征、时空分布规律及主导形成机制。结果表明:①塔秀滩地下水化学类型具有显著空间分异,由山前的HCO3-Ca·Mg型向平原前缘过渡为HCO3·SO4-Ca·Mg型,TDS中位数由113.65 mg/L升至352.95 mg/L;地下水中锶(Sr)含量沿径流路径自补给区的0.11 mg/L递增至排泄区峰值2.46 mg/L,高锶区主要分布于西龙曲—茫拉河交汇带;时序上,地下水锶含量在平水期最高,在丰水期最低,而地表水则在枯水期最高。②水中锶主要来源于三叠系灰岩与第四系粉土,其释放机制包括碳酸盐与硅酸盐矿物溶解及阳离子交换作用;地下水系统尺度上,南部山区富锶基岩经溶解释放锶元素,通过地下水侧向补给进入平原区松散含水层,进一步经历阳离子交换与滞留作用而富集,最终在前缘排泄区达到峰值。本研究系统阐明了青藏高原东北缘共和盆地松散岩类孔隙型富锶地下水的分布特征与形成机制,研究成果可为该类优质矿泉水资源的勘探与可持续开发提供了科学依据。

     

    Abstract: Qinghai Province possesses abundant high-quality natural mineral water resources, particularly characterized by strontium-enriched mineral waters. However, previous studies have primarily focused on strontium-enriched water bodies in karst regions, with limited understanding of the hydrochemical characteristics, spatial distribution patterns of strontium, and enrichment mechanisms in pore-type strontium-enriched groundwater within unconsolidated rock formations. Therefore, this study selected the Taxiutan area in Qinghai’s Gonghe Basin as the research site. A total of 156 water samples and 38 rock and soil samples were collected. By comprehensively applying methods such as the Piper three-line diagram, Pearson correlation analysis, principal component analysis (PCA), and spatial interpolation, this study systematically revealed the hydrochemical characteristics, spatiotemporal distribution patterns, and dominant formation mechanisms of strontium-enriched groundwater in loose rock formations. Results indicate: (1) The groundwater chemistry exhibits significant spatial differentiation, transitioning from HCO3-Ca·Mg type in the foreland to HCO3·SO4-Ca·Mg type at the plain's edge, with median TDS increasing from 113.65 mg/L to 352.95 mg/L. Strontium concentrations in groundwater increased along the runoff path from 0.11 mg/L in the recharge zone to a peak of 2.46 mg/L in the discharge zone, with high-strontium areas primarily distributed in the Xilongqu—Mangla River confluence zone; temporally, groundwater strontium concentrations peaked during normal flow periods and were lowest during high-flow periods, whereas surface water concentrations peaked during low-flow periods. (2) Strontium in water primarily originates from Triassic limestone and Quaternary silt, with release mechanisms including dissolution of carbonate and silicate minerals and cation exchange; At the groundwater system scale, strontium-enriched bedrock in the southern mountainous area releases strontium through dissolution. This strontium enters the loose aquifers of the plain via lateral groundwater recharge, where it undergoes further enrichment through cation exchange and retention processes, ultimately reaching peak concentrations in the foreland discharge zone. This study systematically elucidates the distribution characteristics and formation mechanisms of strontium-enriched groundwater in porous loose rocks within the Gonghe Basin at the northeastern margin of the Tibetan Plateau. The findings provide scientific basis for the exploration and sustainable development of this high-quality mineral water resource.

     

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