基于激光拉曼光谱的非常规油气储层岩石矿物组分快速识别方法研究

Research on Rapid Identification Method of Rock Mineral Components in Unconventional Oil and Gas Reservoirs Based on Laser Raman Spectroscopy

  • 摘要: 对储集层中较为常见的岩石矿物包括单矿物纳米孔隙特征和有机质热成熟度、含量、赋存状态进行研究,可以评价非常规油气储集性能和生烃潜力,也是非常规油气储集层评价工作开展的基础。但在实际应用中,单矿物挑选常会因外形、光性相似而相互混淆,薄片鉴定又会因页岩中矿物颗粒细小而难以有效准确对组分进行辨认,传统的检测有机质成熟度方法也有诸多局限性。为了解决上述问题,本文以激光拉曼光谱快速成像法为基础,通过该方法的点、线、面三种扫描模式,分别对储层中常见的多种单矿物和黑色页岩进行数据采集,结合特征拉曼光谱图的处理以及最终成像,实现对典型矿物组分、空间分布情况和有机质的快速识别和分析,建立了一种多模式扫描矿物组分的快速识别技术手段,并研究该方法在不同形态的样品中的实际应用效果。实验表明,该方法在单矿物中可以有效判断石英、长石和黑云母的存在,识别率100%,且根据长石的474cm−1、513cm−1峰位判断样品中的长石可能为碱性长石中的冰长石;在页岩光薄片的采集区域内识别率为99%~100%,计算各类矿物含量约为石英18%,方解石27%,白云石5%,碳质50%,与薄片鉴定中所获得的矿物信息相似,含量差距在1%~5%。并进一步通过获得的碳质物(1335~1348cm−1、1597~1605cm−1)拉曼光谱图和拉曼特征参数进行观察分析,判断该岩石中至少存在两种以上不同的有机质类型,计算该样品中有机质拉曼反射率(RmcRo%)为2.46%~2.95%,其中类型一介于2.56%~2.95%,类型二介于2.48%~2.81%,前者含量约占扫描范围内有机质总数的72%,后者约为28%。表明该技术在不同形态样品中的实际应用效果良好,可以直观地判断扫描区域内的微细矿物组分、含量以及有机质组成、含量和热演化度等,为非常规油气储层研究提供一种更准确、直观和便捷的分析手段。

     

    Abstract: Studying the nanoscale pore characteristics of common rock minerals in reservoirs, as well as the thermal maturity, content, and occurrence state of organic matter, can help evaluate the unconventional oil and gas storage performance and hydrocarbon generation potential. This also serves as the foundation for unconventional oil and gas reservoir evaluation. However, in practical applications, the selection of single minerals is often prone to confusion due to similar morphology and optical properties, while thin-section identification faces challenges in accurately recognizing components due to the fine-grained minerals in shale. Traditional methods for detecting organic matter maturity also have many limitations. To address these issues, this study employs laser Raman spectroscopy rapid imaging as the basis. Using the point, line, and area scanning modes of this method, data were collected from several common single minerals and black shale in the reservoir. By processing the characteristic Raman spectra and final imaging, rapid identification and analysis of typical mineral components, spatial distribution, and organic matter were achieved. A multimodal scanning technique for the rapid identification of mineral components was proposed, and the practical application effects of this method in samples of different forms were investigated. Experimental results demonstrate that this method can effectively identify the presence of quartz, feldspar, and biotite in single minerals with a 100% recognition rate. Based on the 474cm−1 and 513cm−1 peaks of feldspar, the feldspar in the sample was preliminarily identified as adularia, a type of alkali feldspar. In shale thin sections, the recognition rate was 99%–100%, with calculated mineral contents of approximately 18% quartz, 27% calcite, 5% dolomite, and 50% carbonaceous material, which closely matches the mineral information obtained from thin-section analysis (discrepancy of 1%–5%). Furthermore, by analyzing the Raman spectra (1335–1348cm−1, 1597–1605cm−1) and Raman characteristic parameters of carbonaceous matter, it was determined that at least two different types of organic matter exist in the rock. The calculated Raman reflectance (RmcRo%) of the organic matter in the sample ranged from 2.46% to 2.95%, with TypeⅠ between 2.56%–2.95% (accounting for ~72% of the organic matter in the scanned area) and TypeⅡ between 2.48%–2.81% (~28%). These results indicate that this technique performs well in practical applications across different sample forms, enabling intuitive determination of mineral components, content, organic matter composition, abundance, and thermal maturity within the scanned area. It provides a more accurate, intuitive, and convenient analytical method for unconventional oil and gas reservoir research.

     

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