基于X射线衍射技术研究页岩中非晶质组分与力学性质的关系以四川盆地二叠系吴家坪组页岩储层为例

Investigation of the Relationship between Amorphous Components and Mechanical Properties in Shale Using X-ray Diffraction

  • 摘要: 厘清页岩储层中不同类型非晶质组分含量与岩石力学性质的关系,对深化页岩脆性特征、明确页岩储层压裂改造因素意义重大。然而,页岩储层中不同类型/含量非晶质组分的存在,导致利用X射线衍射分析时因岩石力学权重系数求取不确定,影响页岩整体脆性的量化分析及评价。本文以四川盆地(东部地区)二叠系吴家坪组DY1H井五组典型页岩样品为研究对象,以X射线衍射技术分析为主,并结合岩石薄片鉴定、扫描电镜分析、碳硫分析等实验方法,通过改进的岩石力学权重系数计算方法,对不同类型非晶质组分含量及力学性质关系进行定量分析。结果表明,DY1H井吴家坪组页岩中非晶质组分含量高(平均总质量分数为47.60%),其中无机质组分占比高(平均含量为37.04%)。页岩非晶质组分中的无机组分、有机组分与岩石脆性分别呈较好的正相关及负相关性,指示页岩中非晶质无机组分及有机组分分别具脆性、塑性特征。页岩储层中非晶质有机组分含量差异会影响矿物组分法计算脆性指数的精确性,有机碳含量较低时,可采用矿物组分法计算页岩脆性。此外,页岩中非晶质无机组分含量与黏土矿物中伊蒙混层含量呈正相关性,反映出间层黏土矿物为非晶质无机组分经成岩作用转换所致;页岩中发育较多非晶质无机组分时,需考虑间层黏土矿物的存在会增加页岩塑性。

     

    Abstract: The relationship between the composition of various amorphous components in shale reservoirs and their mechanical properties is crucial for enhancing the understanding of shale brittleness and elucidating the factors that influence the fracturing reconstruction of shale reservoirs. The presence of diverse types and varying quantities of amorphous components in shale reservoirs introduces uncertainty in the determination of rock mechanics weight coefficients when employing X-ray diffraction analysis. This uncertainty subsequently impacts the quantitative assessment of shale brittleness. This study focuses on representative shale samples from the DY1H well (eastern Sichuan Basin). X-ray diffraction technology serves as the primary analytical method, supplemented by experimental techniques such as thin section, scanning electron microscopy, and carbon-sulfur analysis. These methods are employed to quantitatively investigate the relationship between the content of different amorphous components and their mechanical properties through an enhanced calculation method for rock mechanics weight coefficients. The results reveal that the shale from the Permian Wujiaping Formation at the DY1H well possesses a significant proportion of amorphous components, with an average total mass fraction of 47.60%, and a notable predominance of inorganic components, averaging 37.04%. Furthermore, the inorganic and organic components within the amorphous fractions demonstrate both positive and negative correlations with rock brittleness, suggesting that the amorphous inorganic components confer brittle characteristics while the organic components exhibit plastic characteristics. Variations in the content of amorphous organic components within shale reservoirs can influence the precision of brittleness index calculations derived from mineral composition methods. Specifically, when organic carbon content is low, the mineral composition method can be effectively utilized to assess shale brittleness. Additionally, the content of amorphous inorganic components in shale shows a positive correlation with the presence of illite-montmorillonite mixed layers within clay minerals, indicating that these interlayer clay minerals are products of the transformation of amorphous inorganic components during diagenesis. In scenarios where a high abundance of amorphous inorganic components is present in shale, it is crucial to consider the role of interlayer clay minerals, which can improve the plasticity of the shale.

     

/

返回文章
返回