【引用本文】 郑奋, 刘琰, 张红清, . 辽宁岫岩河磨玉岩石地球化学组成及锆石U-Pb定年研究[J]. 岩矿测试, 2019, 38(4): 453-462. doi: 10.15898/j.cnki.11-2131/td.201807310089
ZHENG Fen , LIU Yan , ZHANG Hong-qing . The Petrogeochemistry and Zircon U-Pb Age of Nephrite Placer Deposit in Xiuyan, Liaoning[J]. Rock and Mineral Analysis, 2019, 38(4): 453-462. doi: 10.15898/j.cnki.11-2131/td.201807310089

辽宁岫岩河磨玉岩石地球化学组成及锆石U-Pb定年研究

1. 中国地质大学(北京)珠宝学院, 北京 100083;

2. 中国地质科学院地质研究所, 北京 100037

收稿日期: 2018-07-31  修回日期: 2019-01-25 

基金项目: 中国地质调查局“中国矿产地质志”二级项目(编号DD20160346,DD20190379);自然资源部中国地质调查局地质调查项目(DD20190060);国家自然科学基金项目(41772044)

作者简介: 郑奋,研究生,矿物学、岩石学、矿床学专业。E-mail:864902333@qq.com。。

The Petrogeochemistry and Zircon U-Pb Age of Nephrite Placer Deposit in Xiuyan, Liaoning

1. School of Gemology, China University of Geosciences(Beijing), Beijing 100083, China;

2. Institute of Geology, Chinese Academy of Geological Sciences, Beijing 100037, China

Received Date: 2018-07-31
Revised Date: 2019-01-25

摘要:河磨玉是产于辽宁省岫岩县细玉沟沟谷及白沙河河谷底部和两岸阶地的和田玉,目前仅依据产出位置判断河磨玉来源于细玉沟沟头的原生和田玉矿床,但河磨玉的矿物组成、地球化学特征、年龄等并不清楚,与原生和田玉是否一致有待深入研究。本文主要通过电子探针成分分析、全岩主微量分析、氢氧同位素分析、锆石SHRIMP U-Pb定年等测试方法对河磨玉的矿物组成、地球化学特征及年龄进行研究,确定河磨玉与老玉是否为相同成因。结果表明:①河磨玉中主要矿物为透闪石、阳起石,次要矿物为透辉石、磷灰石、绿泥石、绿帘石、石英、榍石、锆石、磁铁矿、菱锌矿等。②河磨玉的成因类型为大理岩型。河磨玉稀土总量低,相对富集轻稀土,普遍显示Eu正异常。③河磨玉中透闪石δ18O值为8.0‰~10.6‰,δD值为-93.78‰~-75.20‰,成矿流体中的水主要为岩浆水。④河磨玉中的岩浆锆石U-Pb年龄为220.8±7.6Ma(n=4,MSWD=2.3),代表河磨玉成玉年龄的上限。本文提出河磨玉的稀土分配特征、氢氧同位素组成、成矿流体来源及形成年龄均与原生和田玉不一致,河磨玉并非来源于细玉沟沟头的原生和田玉。

关键词: 岫岩, 和田玉, 岩相学, 地球化学特征, SHRIMP锆石U-Pb年龄

The Petrogeochemistry and Zircon U-Pb Age of Nephrite Placer Deposit in Xiuyan, Liaoning

KEY WORDS: Xiuyan, nephrite, petrography, geochemical characteristics, SHRIMP U-Pb age

本文参考文献

[1]

Harlow G E,Sorensen S S.Jade (nephrite and jadeitite) and serpentinite:Metasomatic connections[J].International Geology Review,2005,47(2):113-146.

[2]

Liu Y,Zhang R Q,Zhang Z Y,et al.Mineral inclusions and SHRIMP U-Pb dating of zircons from the Alamas nephrite and granodiorite:Implications for the genesis of a magnesian skarn deposit[J].Lithos,2015,212-215:128-144.

[3]

Liu Y,Zhang R Q,Abuduwayiti M,et al.SHRIMP U-Pb zircon ages,mineral compositions and geochemistry of placer nephrite in the Yurungkash and Karakash River deposits,West Kunlun,Xinjiang,Northwest China:Implication for a magnesium skarn[J].Ore Geology Reviews,2016,72:699-727.

[4]

Yui T F,Kwon S T.Origin of a dolomite-related jade deposit at Chuncheon,Korea[J].Economic Geology,2002,97(3):593-601.

[5]

Liu Y,Deng J,Shi G H,et al.Geochemistry and petrology of nephrite from Alamas,Xinjiang,NW China[J].Journal of Asian Earth Sciences,2011,42(3):440-451.

[6]

Liu Y,Deng J,Shi G H,et al.Geochemistry and petro-genesis of placer nephrite from Hetian,Xinjiang,Northwest China[J].Ore Geology Reviews,2011,41(1):122-132.

[7]

刘喜锋,张红清,刘琰,等.世界范围内代表性碧玉的矿物特征和成因研究[J].岩矿测试,2018,37(5):479-489.

Liu X F,Zhang H Q,Liu Y,et al.Mineralogical characteristics and genesis of green nephrite from the world[J].Rock and Mineral Analysis,2018,37(5):479-489.

[8]

Grapes R H,Yun S T.Geochemistry of a New Zeland nephrite weathering rind[J].New Zealand Journal of Geology and Geophysics,2010,53:413-426.

[9]

Kostov R I,Protochristov C,Stoyanov C,et al.Micro-PIXE geochemical fingerprinting of nephrite neolithic artifacts from South-West Bulgaria[J].Geoarchaeology:An International Journal,2012,27:457-469.

[10]

Siqin B,Qian R,Zhuo S,et al.Glow discharge mass spectrometry studies on nephrite minerals formed by different metal logenic mechanisms and geological environments[J].International Journal of Mass Spectrometry,2012,309:206-211.

[11]

Barnes G L.Understanding Chinese jade in a world con-text[J].Journal of the British Academic,2018,6:1-63.

[12]

王时麒,赵朝洪,于洸,等.中国岫岩玉[M].北京:科学出版社,2007. Wang S Q,Zhao C H,Yu G,et al.Xiuyan Jades in China[M].Beijing:Science Press,2007.

[13]

王时麒,董佩信.岫岩玉的种类、矿床地质特征及成因[J].地质与资源,2011, 20(5):321-331.

Wang S Q,Dong P X.Classification,geologic characteristics and origin of the jade from Xiuyan,Liaoning Province,China[J].Geology and Resources,2011,20(5):321-331.

[14]

丘志力,江启云,落汗,等.辽宁岫岩河磨玉和老玉(闪石玉)中石墨包体的拉曼光谱及其应用[J].光谱学与光谱分析,2010,30(11):2985-2988.

Qiu Z L,Jiang Q Y,Luo H,et al.Raman spectra and its application of graphite enclaves in nephrite-jades in Xiuyan,Liaoning[J].Spectroscopy and Spectral Analysis,2010,30(11):2985-2988.

[15]

Clayton R N,Mayeda T K.The use of bromine penta-fluoride in the extraction of oxygen from oxides and silicates for isotopic analysis[J].Geochimica et Cosmochimica Acta,1963,27(1):43-52.

[16]

Friedman I.Deuterium content of natural waters and other substances[J].Geochimica et Cosmochimica Acta,1953,4(1-2):89-103.

[17]

Black L P,Kamo S L,Allen C M,et al.TEMORA 1:A new zircon standard for Phanerozoic U-Pb geochrono-logy[J].Chemical Geology,2003,200(1):155-170.

[18]

Nasdala L,Hofmeister W,Norberg N,et al.Zircon M257-A homogeneous natural reference material for the ion microprobe U-Pb analysis of zircon[J].Geostandards and Geoanalytical Research,2008,32(3):247-265.

[19]

Black L P,Kamo S L,Williams I S,et al.The application of SHRIMP to Phanerozoic geochronology:A critical appraisal of four zircon standards[J].Chemical Geology,2003,200:171-188.

[20]

Ludwig K R.SQUID 1.02,A User'S Manual[M].Ber-keley Geochronology Center Special Publication No.2.2455 Ridge Road,Berkeley,CA 94709,USA,2002.

[21]

Stacey J S,Kramers J D.Approximation of terrestrial lead isotope evolution by a two-stage model[J].Earth & Planetary Science Letters,1975,26:207-221.

[22]

Adamo I,Bocchio R.Nephrite jade from Val Malenco,Italy:Review and update[J].Gems and Gemology,2013,49:98-106.

[23]

Yui T F,Yeh H W,Wang L C.Stable isotope studies of nephrite deposits from Fengtien, Taiwan[J].Geochimica et Cosmochimica Acta,1988,52:593-602.

[24]

郑永飞,徐宝龙,周根陶.矿物稳定同位素地球化学研究[J].地学前缘,2000,7(2):299-320.

Zheng Y F,Xu B L,Zhou G T.Geochemical studies of stable isotopes in minerals[J].Earth Science Frontiers,2000,7(2):299-320.

[25]

Graham C H,Harmon R S,Sheppard S M F.Experi-mental hydrogen isotope studies:Hydrogen isotope exchange between amphilbole and water[J].American Mineralogist,1984,69:128-138.

[26]

Taylor Jr H P.Oxygen and Hydrogen Isotope Relation-ships in Hydrothermal Mineral Deposits[C]//Barnes H L.Geochemistry of Hydrothermal Ore Deposits (3rd Edition).New York:Wiley-Interscience,1997:229-302.

[27]

Gil G,Barnes J D,Boschi C,et al.Nephrite from Złoty Stok (Sudetes,SW Poland):Petrological,geochemical and isotopic evidence for a dolomite-related origin[J].The Canadian Mineralogist,2015,53(3):533-556.

[28]

李长民.锆石成因矿物学与锆石微区定年综述[J].地质调查与研究,2009,33(3):161-174.

Li C M.A review on the minerageny and situ microanalytical dating techniques of zircons[J].Geological Survey and Research,2009,33(3):161-174.

[29]

李大中,于士祥,王泽.辽宁岫岩地区岫玉成矿规律探讨[J].地质找矿论丛,2013,28(2):249-255.

Li D Z,Yu S X,Wang Z.Discussion on the jade-forming regularity of Xiuyan jade in Xiuyan area,Liaoning Province[J].Contributions to Geology and Mineral Resources Research,2013,28(2):249-255.

[30]

刘喜锋,刘琰,李自静,等.新疆皮山镁质矽卡岩矿床(含糖玉)成因及锆石SHRIMP U-Pb定年[J].岩石矿物学杂志,2017,36(2):259-273.

Liu X F,Liu Y,Li Z J,et al.The genesis of Mg-skarn deposit (bearing brown nephrite) and its Ar-Ar dating of phlogopite and SHRIMP U-Pb dating of zircon,Pishan,Xinjiang[J].Acta Petrologica et Mineralogica,2017,36(2):259-273.

[31]

张勇,魏华,陆太进,等.新疆奥米夏和田玉矿床成因及锆石LA-ICP-MS定年研究[J].岩矿测试,2018,37(6):695-704.

Zhang Y,Wei H,Lu T J,et al.The genesis and LA-ICP-MS zircon ages of the Omixia nephrite deposit,Xinjiang,China[J].Rock and Mineral Analysis,2018,37(6):695-704.

[32]

贾玉衡,刘喜锋,刘琰,等.新疆且末碧玉矿的成因研究[J].岩石矿物学杂志,2018,37(5):824-838.

Jia Y H,Liu X F,Liu Y,et al.Petrogenesis of the serpentinite-related nephrite deposit in Qiemo County,Xinjiang[J].Acta Petrologica et Mineralogica,2018,37(5):824-838.

相似文献(共19条)

[1]

刘明华, 杨晓波, 佟成冶, 马力, 乌爱军. 辽宁省浑河流域底质中重金属元素地球化学特征. 岩矿测试, 2008, 27(3): 184-188.

[2]

张勇, 魏华, 陆太进, 陈华, 韩冬, 冯晓燕, 买托乎提·阿不都瓦衣提. 新疆奥米夏和田玉矿床成因及锆石LA-ICP-MS定年研究. 岩矿测试, 2018, 37(6): 695-704. doi: 10.15898/j.cnki.11-2131/td.201801170007

[3]

谢奋全, 王黎栋, 李琦, 石朝霞, 陈学兵, 韦岸. 阿拉善宗乃山岩体东南缘花岗岩LA-ICP-MS锆石U-Pb年龄与地球化学特征. 岩矿测试, 2015, 34(3): 375-382. doi: 10.15898/j.cnki.11-2131/td.2015.03.019

[4]

赵泽霖, 李俊建, 党智财, 付超, 唐文龙, 王守光, 刘利双, 赵丽君. 内蒙古黄花滩铜镍矿区辉长岩LA-ICP-MS锆石U-Pb定年及地球化学特征. 岩矿测试, 2016, 35(2): 208-216. doi: 10.15898/j.cnki.11-2131/td.2016.02.014

[5]

潘小川, 刘晓端, 李奇, 葛晓立, 罗松光. 密云水库水体的地球化学特征. 岩矿测试, 2003, (1): 44-48.

[6]

文春华, 罗小亚, 李胜苗, 李建康. 应用X射线荧光光谱-电感耦合等离子体质谱法研究湖南传梓源地区稀有金属矿床伟晶岩地球化学特征. 岩矿测试, 2015, 34(3): 359-365. doi: 10.15898/j.cnki.11-2131/td.2015.03.017

[7]

庞绪贵, 王增辉, 赵西强, 胡雪平, 滕兆令, 李秀章. 山东省黄河下游地区浅层地下水地球化学特征. 岩矿测试, 2007, 26(4): 298-304.

[8]

赵庆令, 安茂国, 陈洪年, 吴晓华, 李清彩, 王彩. 济南市某废弃化工厂区域土壤地球化学特征研究. 岩矿测试, 2018, 37(2): 201-208. doi: 10.15898/j.cnki.11-2131/td.201708240135

[9]

陈富荣, 史春鸿, 梁红霞. 中国南部湿润半湿润丘陵山区不同粒级水系沉积物地球化学特征对比研究. 岩矿测试, 2017, 36(2): 136-145. doi: 10.15898/j.cnki.11-2131/td.2017.02.007

[10]

何晗晗, 李建康, 李超, 苏晓云, 赵芝, 张怡军, 王国瑞. 湘南骑田岭矿集区深部探测剖面的稀土元素地球化学特征. 岩矿测试, 2014, 33(1): 110-117.

[11]

苏晓云, 刘善宝, 高虎, 王成辉, 刘战庆, 胡正华, 刘建光, 陈国华, 万浩章. 基于电感耦合等离子体质谱/光谱技术研究朱溪钨铜矿床原生晕地球化学特征. 岩矿测试, 2015, 34(2): 252-260. doi: 10.15898/j.cnki.11-2131/td.2015.02.017

[12]

苏晓云, 王登红, 王成辉, 刘善宝, 刘建光, 樊兴涛, 蒯丽君, 陈国华, 万浩章, 张诚, 黄桂强. 基于XEPOS型X射线荧光光谱仪研究江西朱溪铜钨矿床成矿元素地球化学特征与成因. 岩矿测试, 2013, 32(6): 959-969.

[13]

王永, 陈正乐, 陈柏林, 董法宪, 张海东, 韩凤彬, 周永贵. 山西平顺西安里铁矿区中生代闪长岩年代学及地球化学特征. 岩矿测试, 2013, 32(1): 131-144.

[14]

黄增芳, 苏美霞, 王忠, 李世宝, 王喜宽, 赵锁志, 张青. 河套地区土壤基准值及背景值特征. 岩矿测试, 2007, 26(4): 287-292.

[15]

谢忠, 边维勇, 佟成冶, 马力, 杨晓波. 矿山开采对辽宁柴河流域生态环境的影响. 岩矿测试, 2007, 26(4): 293-297.

[16]

陈芳, 杜建国, 万秋, 邱军强, 汤金来. 北淮阳东段徐家湾岩体地质和地球化学特征及LA-ICP-MS锆石U-Pb年龄. 岩矿测试, 2016, 35(3): 329-338. doi: 10.15898/j.cnki.11-2131/td.2016.03.017

[17]

杨军华. 福建沿海地区芦柑的地质环境适宜性评价. 岩矿测试, 2007, 26(4): 269-274.

[18]

胡雪原, 郭瑞清, 努尔喀纳提·马达依普, 郭羽, 邹明煜, 吕彪, 魏震. 塔里木南缘布雅花岗岩和暗色包体的锆石U-Pb年代学及地球化学特征. 岩矿测试, 2017, 36(5): 538-550. doi: 10.15898/j.cnki.11-2131/td.201703190035

[19]

王先广, 刘战庆, 刘善宝, 王成辉, 刘建光, 万浩章, 陈国华, 张树德, 刘小林. 江西朱溪铜钨矿细粒花岗岩LA-ICP-MS锆石U-Pb定年和岩石地球化学研究. 岩矿测试, 2015, 34(5): 592-599. doi: 10.15898/j.cnki.11-2131/td.2015.05.016

计量
  • PDF下载量(10)
  • 文章访问量(129)
  • 被引次数(0)
目录

Figures And Tables

辽宁岫岩河磨玉岩石地球化学组成及锆石U-Pb定年研究

郑奋, 刘琰, 张红清