【引用本文】 李超, 王登红, 屈文俊, 等. 关键金属元素分析测试技术方法应用进展[J]. 岩矿测试, 2020, 39(5): 658-669. doi: 10.15898/j.cnki.11-2131/td.201907310115
LI Chao, WANG Deng-hong, QU Wen-jun, et al. A Review and Perspective on Analytical Methods of Critical Metal Elements[J]. Rock and Mineral Analysis, 2020, 39(5): 658-669. doi: 10.15898/j.cnki.11-2131/td.201907310115



国家地质实验测试中心, 北京 100037


中国地质科学院矿产资源研究所, 北京 100037


昆明理工大学国土资源工程学院, 云南 昆明 650093

收稿日期: 2019-07-31  修回日期: 2020-01-11  接受日期: 2020-04-16

基金项目: 国家自然科学基金项目(41673060,41873065);国家重点研发计划专项(2017YFC0602700)

作者简介: 李超, 博士, 副研究员, 从事地质样品分析测试研究。E-mail:Re-Os@163.com

A Review and Perspective on Analytical Methods of Critical Metal Elements


National Research Center for Analysis, Beijing 100037, China


Institute of Mineral Resources, Chinese Academy of Geological Sciences, Beijing 100037, China


Faculty of Land Resource Engineering, Kunming University of Science and Technology, Kunming 650093, China

Received Date: 2019-07-31
Revised Date: 2020-01-11
Accepted Date: 2020-04-16


关键词: 关键金属元素, 赋存基体, 样品处理方法, 分析测试技术, 微区原位分析, 野外现场分析


(1) 关键金属元素以其不常见、分布不均、基体复杂等特点,对分析测试提出了新的挑战。

(2) 评述了样品难溶、回收不完全、测试干扰、基体效应等影响测试的主要因素。

(3) 总结了硅酸盐、碳酸盐、氧化物、硫化物等不同基体样品的化学前处理方法。

(4) 微区原位分析和野外现场分析是关键金属元素分析技术发展的趋势。

A Review and Perspective on Analytical Methods of Critical Metal Elements



Strategic critical metal mineral resources including rare, dispersed, rare earth and platinum group elements play an increasingly critical role in emerging industries such as new materials, new energy and information technology. With the deepening of the geological survey of key mineral resources in China, the critical metal elements present new challenges to analytical techniques due to their complex matrix, large differences in different mineral contents, and unstable chemical properties.


To introduce recent analytical techniques and applications for critical metal elements in different types of geological samples.


Based on different chemical composition, the main matrices of critical metal elements were classified, mainly divided into silicate, carbonate, sulfate, tungstate, phosphate, oxide, sulfide and halide. For different types of rocks and minerals, chemical digestion was largely carried out by traditional dissolution methods such as the acid dissolution method (nitric acid-hydrofluoric acid combination, aqua regia) or alkali fusion methods.


The characteristics and application of commonly used instruments including electronic probe microanalyzer, inductively coupled plasma-mass spectrometry, inductively coupled plasma-optical emission spectroscopy, and X-ray fluorescence spectroscopy were reviewed. The problems during critical metal analysis including incomplete dissolution, low recovery, oxides and isobaric interference, inconsistency between samples and standard matrices were reviewed and corresponding solutions were proposed.


In situ microanalysis with the advantages of high efficiency, low cost, and high spatial resolution, and field on-site geoanalysis with its simple, fast and close to field work features are the main trends in the development of critical metal elements analytical techniques.

KEY WORDS: critical metal elements, occurrence matrix, sample pretreatment methods, analytical technique, in situ microanalysis, field on-site geoanalysis


(1) Critical metal elements present new challenges for analytical techniques due to their uncommon, unevenly distributed, and complex matrix characteristics.

(2) Incomplete dissolving of minerals, extraction of elements, matrix effect between sample and standard solution, and interferences are main challenges in critical metal elements analysis.

(3) The chemical preparation procedures for the different minerals such as silicate, carbonate, oxide and sulfide were summarized.

(4) Microarea in situ analysis and field on-site analysis are the development trend of critical metal elements analysis.



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